Flag | Nation | Road Race | Time Trial |
| Albania | Eugert Zhupa (UPC - Boehringer) | Eugert Zhupa (UPC - Boehringer) |
| Algeria | Abdalla Ben Youcef (MTN-WBR) | Abdelmalek Madani (Jaguar) |
| Argentina | Pedro Pablo Pereyra (Lotto - Cervelo) | Eduardo Sepulveda (Metinvest-Emirates) |
| Australia | Wes Sulzberger (Simply Red Bull) | Michael Rogers (Oz) |
| Austria | Bernhard Eisel (AMEX Pro Cycling) | Matthias Brändle (VW-Mapei) |
| Belarus | Andrei Sakalou (Tinkoff) | Vasili Kiryenka (Tinkoff) |
| Belgium | Philipe Gilbert (Pendelton's) | Dominique Cornu (Bpost) |
| Bermuda | Tyler Butterfield (Bacardi) | Tyler Butterfield (Bacardi) |
| Bolivia | Piter Campero (Festina-Canal+) | Ruben Ibanez (Pendleton's) |
| Brazil | Rafael Andriato (Repsol-Cativen) | Pedro Nicácio (Prio-Porto) |
| Bulgaria | Stefan Hristov (Boeing-Vivacom) | Nikolay Mihaylov (Boeing-Vivacom) |
| Burkina Faso | Salfo Bikienga (PFG-Armavia) | Oumaru Minoungo (Pendleton's) |
| Cameroon | Ngue Yves Ngock (MTN-WBR) | Ngue Yves Ngock (MTN-WBR) |
| Canada | Christian Meier (Alstom-RBC) | Christian Meier (Alstom-RBC) |
| Chile | Carlos Oyarzun (Pendleton's) | Sergio Ortega (Repsol-Cativen) |
| China | Biao Liu (PFG-Armavia) | Haijun Ma (Metinvest-Emirates) |
| Colombia | Cayetano Sarmiento (Evian-MIAT) | Rigoberto Úran (Milka - AVG) |
| Costa Rica | Marco Salas (BNCR) | Andrei Amador (UBS - BMC) |
| Croatia | Pavel Potocki (HTC Nieuwsblad) | Kristijan Durasek (Alstom-RBC) |
| Cuba | Jose Mojica (Mobil - Castrol) | Jose Mojica (Mobil - Castrol) |
| Curaçao | Marc De Maar (HTC Nieuwsblad) | Marc De Maar (HTC Nieuwsblad) |
| Cyprus | Vassilis Adamou (PFG-Armavia) | Marios Athanasiades (Team Privatbank) |
| Czech Republic | Jakub Novak (Milka - AVG) | Roman Kreuziger (Milka - AVG) |
| Denmark | Matti Breschel (AMEX Pro Cycling) | André Steensen (Team B&O) |
| Egypt | Cherif Abdallah (MTN-WBR) | Cherif Abdallah (MTN-WBR) |
| Eritrea | Meron Russom (Pendleton's) | Daniel Teklehaimanot (Jaguar - Eritel) |
| Estonia | Rein Taaramäe (Bouygues) | Rein Taaramäe (Bouygues) |
| Ethiopia | Tsgabu Gebremaryam Grmay (PFG-Armavia) | Estifanos Kebede (Repsol-Cativen) |
| Finland | Olli Kulppi (HTC Niuwsbald) | Olli Kulppi (HTC Nieuwsblad) |
| France | Cyril Gautier (Team BPost) | Jerome Coppel (Milka - AVG) |
| FYROM | Stefan Petrovski (Metinvest-Emirates) | Stefan Petrovski (Metinvest-Emirates) |
| Gabon | Amadou Bakari (Boeing) | Charles Anguilet (Jaguar-Eritel) |
| Georgia | Irakli Bablidze (Bouygues) | Irakli Bablidze (Bouygues) |
| Germany | Stefan Schumacher (UBS-BMC) | Jacob Fiedler (Koenigsegg) |
| Great Britain | Alex Dowsett (Jaguar - Eritel) | Ian Bibby (Jaguar - Eritel) |
| Greece | Charalampas Kastrantas (Evian-MIAT) | Panagiotis Vlatos (Festina-Canal+) |
| Hong Kong | Kin-San Wu (Oz Cycling) | Ho-Ting Kwok (Meiji - Cannondale) |
| Hungary | Peter Kusztor (Metinvest-Emirates) | Peter Kusztor (Metinvest-Emirates) |
| Indonesia | Jimmy Pranata (PFG-Armavia) | Jimmy Pranata (PFG-Armavia) |
| Iran | Mahdi Sohrabi (PFG-Armavia) | Abolfazl Gilanpoor (Heineken) |
| Ireland | Paidi O'Brien (Magna-Ryanair) | Martyn Irvine (Adira-Isq) |
| Israel | Daniel Eliad (Kenya Airways) | Roy Goldstein (Evian-MIAT) |
| Italy | Diego Ulissi (Festina - Canal+) | Vincenzo Nibali (UBS - BMC) |
| Ivory Coast | Issiaka Cisse (Jaguar) | Issiaka Cisse (Jaguar) |
| Japan | Yusuke Hatanaka (Meiji - Cannondale) | Junya Sano (Meiji - Cannondale) |
| Kazakhstan | Chu Thien Sinelobov (UBS - BMC) | Andrei Kashechkin (Repsol-Cativen) |
| Kenya | Daniel Njoroge (Kenya Airways) | Mujtaba Hussein (Kenya Airways) |
| Latvia | Andzs Flaksis (Wikipedia) | Arturs Ansons (Privatbank) |
| Liechtenstein | Benedikt Mundle (Sauber Petronas) | Dimitri Jiriakov (Sauber) |
| Lithuania | Gediminas Bagdonas (Bacardi) | Ramunas Navardauskas (Festina-Canal+) |
| Luxembourg | Gilles Heymes (airBaltic - Endura) | Nick Clesen (Cisco) |
| Malaysia | Anuar Manan (Meiji - Cannondale) | Azizulhasni Awang (Sauber Petronas Racing) |
| Mexico | Bernardo Colex (BNCR) | Bernardo Colex (BNCR) |
| Moldova | Nicolae Tanovitchii (Team Privatbank) | Aleksandr Pluchkin (Team B&O) |
| Mongolia | Sonomtseren Delgerbayar (Oz Cycling) | Maani Altanzul (Evian-MIAT) |
| Morocco | Soufiane Haddi (FC Barcelona) | Adil Jelloul (Simply RB) |
| Namibia | Ermin Van Wyk (airBaltic) | Dan Craven (Pro Team Venchi - Sugoi) |
| Netherlands | Maurice Schreurs (Team Vueling Airlines) | Joost Posthuma (Project 1t4i) |
| New Zealand | Hayden Roulston (WWE) | Jesse Sergent (Milka - AVG) |
| Norway | Bjørn Tore Holm (Cisco) | Sten Stenersen (Team B&O) |
| Poland | Adrian Honkisz (Credexbank) | Przemyslaw Niemiec (Credexbank) |
| Portugal | Amaro Antunes (Adira-Isq) | Nelson Oliveira (Prio - Porto) |
| Qatar | Ahmed Albourdainy (Metinvest-Emirates) | Ahmed Albourdainy (Metinvest-Emirates) |
| Romania | George Alexandru Stancu (Swedbank-PEAB) | Andrei Nechita (Project 1t4i) |
| Russia | Sergey Firsanov (BNCR) | Yuri Trofimov (Koenigsegg) |
| Rwanda | Janvier Hadi (Jaguar - Eritel) | Joseph Biziyaremye (Aker-MOT) |
| San Marino | Marco Zafferani (Wiggle) | Paolo Scarponi (Wiggle) |
| Serbia | Gabor Kasa (Adira-Isq Project) | Nebojsa Jovanovic (Pendleton's) |
| Slovakia | Robert Gavenda (PFG-Armavia) | Peter Velits (Project 1t4i) |
| Slovenia | Jure Kocjan (Team Bacardi) | Simon Spilak (Aker - MOT) |
| South Africa | Nolan Hoffman (Metinvest-Emirates) | Reinhardt Janse van Rensburg (Wikipedia) |
| South Korea | Sung Baek Park (Meiji - Cannondale) | Sung Baek Park (Meiji - Cannondale) |
| Spain | Angel Madrazo (Santander) | Justo Tenorio (Santander) |
| Sweden | Max Öste-Macdonald (Koenigsegg) | Johan Lindgren (Swedbank-PEAB) |
| Switzerland | Johann Tschopp (UBS-BMC) | Fabian Cancellara (Simply Red Bull) | |
| Taiwan | Chun Kai Feng (PFG-Armavia) | Chun Kai Feng (PFG-Armavia) |
| Thailand | Thurakit Boonratanathanakorn (Simply Red Bull) | Phucong Sai-Udomsin (PFG-Armavia) |
| Tunisia | Riadh Ghdamsi (Kenya Airways) | Riadh Ghdamsi (Kenya Airways) |
| Turkey | Gökhan Hasta (Adira-Isq) | Gökhan Hasta (Adira-Isq) |
| UAE | Yousef Mirzah Banihammad (PFG-Armavia) | Yousef Mirzah Banihammad (PFG-Armavia) |
| Ukraine | Artem Topchanyuk (Aker - MOT) | Dmitri Grabovski (Team B&O) |
| Uruguay | Fabricio Ferrari (Mobil - Castrol) | Jorge Adelbo Soto Pereira (Adira-Isq) |
| USA | Joseph Dombrowski (WWE) | David Zabriskie (ING) |
| Uzbekistan | Sergei Lagutin (Meiji - Cannondale) | Sergei Lagutin (Meiji - Cannondale) |
| Venezuela | Yeison Delgado (VW - Mapei) | José Rujano (Pokerstars.com) |